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Modification of poly(styrene‐b‐(ethylene‐co‐butylene)‐b‐styrene) via free‐radical grafting and its photo‐crosslinking

Abstract : Poly(styrene-b-(ethylene-co-butylene)-b-styrene) (SEBS) is functionalized via radical grafting with 4-vinyl-1-cyclohexene 1,2-epoxide (VCHO) initiated using 2,5-Bis(tert-butylperoxy)-2,5-dimethylhexane. The existence of the epoxide group on the SEBS backbone is evidenced by 1H nuclear magnetic resonance. A size exclusion chromatography (SEC) study reveals some chain coupling, and this phenomenon is limited by controlling the quantities of peroxide and monomer reagents used during the radical grafting. Photo-crosslinking of SEBS-g-VCHO under ultraviolet irradiation in the presence of a cationic initiator is then successfully performed with resultant gel contents higher than 85%. Mechanical properties of SEBS and crosslinked materials are measured by tensile tests on thin films. On the one hand, those tests reveal a significant increase of Young's modulus of the crosslinked materials. On the other hand, the diminution of elongation at break is much more limited; crosslinked materials retain their elastomeric properties with an elongation at break greater than 200%. Finally, the photosensitive SEBS-g-VCHO is used to show the adhesion performance of the photo-crosslinking coating as well as a resin for the stereolithography process.
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Submitted on : Thursday, December 9, 2021 - 1:23:10 PM
Last modification on : Friday, August 5, 2022 - 10:59:24 AM


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Agnès Harlay, Thomas Brossier, Nicolas Morand, Marcos Batistella, Arnaud Regazzi, et al.. Modification of poly(styrene‐b‐(ethylene‐co‐butylene)‐b‐styrene) via free‐radical grafting and its photo‐crosslinking. Polymer Engineering and Science, Wiley-Blackwell, 2021, 61 (12), p. 3082-3093. ⟨10.1002/pen.25820⟩. ⟨hal-03390448⟩



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