, background salt NaCl 1 M (dashed lines) and 0.1 M
, Figure S2: Effect of equilibrium pH on the distribution ratio of U(VI) (log 10 plot) for APEI and Q-APEI sorbents
, Figure S4: Variation of pH during U(VI) sorption using APEI and Q-APEI sorbents (Sorbent dosage, SD: 0.333 g L ?1 ; contact time: 48 h; agitation speed: 170 rpm; T: 22 ± 2 ? C). Figure S5: U(VI) uptake kinetics using Q-APEI sorbent-Modeling with the PSORE (a) and the RIDE (b) (SD: 0.3 g L ?1 ; pH 0 : 4; pH eq : 3.79-3.71; C 0 : 0.214 mmol U L ?1 and 0.249 mmol U L ?1 for 1st and 2nd series, respectively; agitation speed: 170 rpm; T: 22 ± 2 ? C). Figure S6: Semi-quantitative EDX analysis of copper-cake collected after cementation. Figure S7: Semi-quantitative EDX analysis of iron-cake after pH control at pH 5. Figure S8: Effect of time on uranium sorption from multi-component solutions (C 0 : 350-346 mg U L ?1 = 1.47-1.45 mmol U L ?1 ; T: 22 ± 2 ? C; SD: 0.125 g L ?1 ; agitation speed: 170 rpm), Figure S3: U(VI) speciation in function of pH (a) and total metal concentration at pH 4 (b) (following the experimental conditions relevant to pH study and sorption isotherms, respectively; calculations performed using Visual Minteq, vol.81
, mg U L ?1 = 1.47-1.45 mmol U L ?1 ; SD: 0.125 g L ?1 ; agitation speed: 170 rpm; agitation time: 24 h). Figure S11. Semi-quantitative analysis of the yellow cake produced from the eluates of sorbent after U-loading from ore leachates at pH 2 and pH 4. Figure S12: Alloga locality of Abu Zienema area, mg Fe L ?1 = 34.47 mmol Fe L ?1, pp.350-346
Recovery of uranium and copper from mineralized dolostone, Gabal Allouga, Southwestern Sinai, Egypt, J. Radiat. Res. Appl. Sci, vol.12, pp.10-23, 2019. ,
Leaching behavior of uranium and vanadium using strong sulfuric acid from Korean black shale ore, J. Radioanal. Nucl. Chem, vol.299, pp.81-87, 2014. ,
Preparation of a uranium leach liquor from a refractory ore using nitric acid solution, Int. J. Environ. Anal. Chem, vol.2019, pp.1-24 ,
A comparison of uranium recovery from low-grade ore by bioleaching and acid leaching, Physicochem. Probl. Miner. Process, vol.53, pp.136-149, 2017. ,
Uranium leaching using citric acid and oxalic acid, J. Radioanal. Nucl. Chem, vol.321, pp.815-822, 2019. ,
Integrated treatment of tailing material for the selective recovery of uranium, rare earth elements and heavy metals, Miner. Eng, vol.133, pp.138-148, 2019. ,
URL : https://hal.archives-ouvertes.fr/hal-02425057
Modeling of the solvent extraction equilibrium of uranium(VI) sulfate with Alamine 336, Braz. J. Chem. Eng, vol.34, pp.355-362, 2017. ,
Solvent extraction of uranium from leach solutions obtained in processing of Polish low-grade ores, J. Radioanal. Nucl. Chem, vol.311, pp.589-598, 2017. ,
Uranium recovery from strong acidic solutions by solvent extraction with Cyanex 923 and a modifier, Miner. Eng, vol.89, pp.77-83, 2016. ,
Sorption behaviour of uranium(VI) with N,N-dibutyl-N '-benzoylthiourea Impregnated in Amberlite XAD-16, Talanta, vol.55, p.23, 2001. ,
Kinetic, equilibrium and thermodynamic studies on sorption of uranium and thorium from aqueous solutions by a selective impregnated resin containing carminic acid, J. Hazard. Mater, vol.286, pp.152-163, 2015. ,
Study of uranium sorption using D2EHPA-impregnated polymeric beads, J. Appl. Polym. Sci, vol.130, pp.3355-3364, 2013. ,
Biosorption of uranium(VI) by free and entrapped Chlamydomonas reinhardtii: Kinetic, equilibrium and thermodynamic studies, J. Radioanal. Nucl. Chem, vol.299, 1993. ,
Mechanism of uranium(VI) uptake by Saccharomyces cerevisiae under environmentally relevant conditions: Batch, HRTEM, and FTIR studies, J. Hazard. Mater, vol.262, pp.297-303, 2013. ,
Uranium adsorption by non-treated and chemically modified cactus fibres in aqueous solutions, J. Radioanal. Nucl. Chem, vol.298, pp.1587-1595, 2013. ,
Comparative study of lanthanum, vanadium, and uranium bioremoval using different types of microorganisms, Water Air Soil Pollut, vol.229, 2018. ,
The effectiveness of ion exchange resins in separating uranium and thorium from rare earth elements in acidic aqueous sulfate media. Part 2. Chelating resins, Miner. Eng, vol.123, pp.8-15, 2018. ,
Synthesis of phosphorus-modified poly(styrene-co-divinylbenzene) chelating resin and its adsorption properties of uranium(VI), J. Radioanal. Nucl. Chem, vol.298, pp.1137-1147, 2013. ,
Recovery of uranium from phosphoric acid solutions using chelating ion-exchange resins, Ind. Eng. Chem. Res, vol.37, 1983. ,
Synthesis of new type dipropyl imide chelating resin and its potential for uranium(VI) adsorption, J. Radioanal. Nucl. Chem, vol.318, pp.1219-1227, 2018. ,
The effect of contaminants on the application of polyamine functionalised ion exchange resins for uranium extraction from sulfate based mining process waters, Chem. Eng. J, vol.354, pp.633-640, 2018. ,
Ethylenediamine-funtionalized ion exchange resin for uranium recovery from acidic mixed sulphate-chloride media: Initial column loading studies, J. South Afr. Inst. Min. Metall, vol.118, pp.1251-1257, 2018. ,
The effect of uranium speciation on the removal of gross alpha activity from acid mine drainage using anion exchange resin, J. Radioanal. Nucl. Chem, vol.319, pp.357-363, 2019. ,
SOHIO process legacy waste treatment: Uranium recovery using ion exchange, J. Ind. Eng. Chem, vol.81, pp.144-152, 2020. ,
Studies on lowering of uranium from mine water by static bed ion exchange process, Sep. Sci. Technol, vol.54, pp.1607-1619, 2019. ,
Kinetic study of ultrasonic-assisted uranium adsorption by anion exchange resin, Colloids Surf, vol.2020, 124021. ,
Uranium extraction by sulfonated mesoporous silica derived from blast furnace slag, J. Nucl. Mater, vol.509, pp.295-304, 2018. ,
Phosphoryl functionalized mesoporous silica for uranium adsorption, Appl. Surf. Sci, vol.402, pp.53-60, 2017. ,
Sorption of uranium from radioactive wastes by silicate-neutralised polyacrylic, Int. J. Environ. Anal. Chem, vol.2019, pp.1-16 ,
Uranium sorption onto mullite: Characteristics of isotherms, kinetics and thermodynamics, J. Earth Syst. Sci, vol.128, pp.12-21, 2019. ,
Preconcentration of uranium(VI) from aqueous solution by amidoxime-functionalized microspheres silica material: Kinetics, isotherm and mechanism study, vol.3, pp.12346-12356, 2018. ,
Emerging natural and tailored materials for uranium-contaminated water treatment and environmental remediation, Prog. Mater. Sci, vol.103, pp.180-234, 2019. ,
Highly efficient immobilization of uranium(VI) from aqueous solution by phosphonate-functionalized dendritic fibrous nanosilica (DFNS), J. Hazard. Mater, vol.363, pp.248-257, 2019. ,
Efficient and selective separation of U(VI) and Th(IV) from rare earths using functionalized hierarchically mesoporous silica, J. Mater. Sci, vol.53, pp.3398-3416, 2018. ,
Uranium biosorption by a filamentous fungus Mucor miehei: pH effect on mechanisms and performances of uptake, Water Res, vol.26, pp.1139-1145, 1992. ,
U(VI) and Sr(II) batch sorption and diffusion kinetics into mesoporous silica (MCM-41), Chem. Geol, vol.390, pp.152-163, 2014. ,
Alginate and algal-based beads for the sorption of metal cations: Cu(II) and Pb(II), Int. J. Mol. Sci, vol.17, 1453. ,
URL : https://hal.archives-ouvertes.fr/hal-01680980
A comparison of palladium sorption using polyethylenimine impregnated alginate-based and carrageenan-based algal beads, Appl. Sci.-Basel, 2018. ,
URL : https://hal.archives-ouvertes.fr/hal-01757167
A new method for incorporating polyethyleneimine (PEI) in algal beads: High stability as sorbent for palladium recovery and supported catalyst for nitrophenol hydrogenation, Mater. Chem. Phys, vol.221, pp.144-155, 2019. ,
URL : https://hal.archives-ouvertes.fr/hal-01937653
Amidoxime functionalization of algal/polyethyleneimine beads for the sorption of Sr(II) from aqueous solutions, Molecules, vol.24, 2019. ,
URL : https://hal.archives-ouvertes.fr/hal-02345894
Quaternization of algal/PEI beads (a new sorbent): Characterization and application to scandium recovery from aqueous solutions, Chem. Eng. J, 2020. ,
Selenium(VI) and copper(II) adsorption using polyethyleneimine-based resins: Effect of glutaraldehyde crosslinking and storage condition, J. Hazard. Mater, 2019. ,
URL : https://hal.archives-ouvertes.fr/hal-02456548
Layered metal sulfides capture uranium from seawater, JACS, vol.134, pp.16441-16446, 2012. ,
PANI/GO as a super adsorbent for the selective adsorption of uranium(VI), Chem. Eng. J, vol.255, pp.604-612, 2014. ,
Synthesis and adsorption characteristics of grafted hydrazinyl amine magnetite-chitosan for Ni(II) and Pb(II) recovery, Chem. Eng. J, vol.362, pp.310-324, 2019. ,
URL : https://hal.archives-ouvertes.fr/hal-02425055
Rodriguez-Castellon, E. Formation of complexes between functionalized chitosan membranes and copper: A study by angle resolved XPS, Mater. Chem. Phys, vol.185, pp.152-161, 2017. ,
Direct synthesis of bacteria-derived carbonaceous nanofibers as a highly efficient material for radionuclides elimination, ACS Sustain. Chem. Eng, vol.4, pp.4608-4616, 2016. ,
Modification of surface-oxidized copper alloy by coupling of viologens for inhibiting microbiologically influenced corrosion, J. Electrochem. Soc, vol.154, pp.645-657, 2007. ,
Studies on salophen anchored micro/meso porous activated carbon fibres for the removal and recovery of uranium, RSC Adv, vol.5, pp.33023-33036, 2015. ,
Amidoxime functionalization of a poly(acrylonitrile)/silica composite for the sorption of Ga(III)-Application to the treatment of Bayer liquor, Chem. Eng. J, vol.368, pp.459-473, 2019. ,
URL : https://hal.archives-ouvertes.fr/hal-02428222
A graphene oxide/amidoxime hydrogel for enhanced uranium capture, Sci. Rep, vol.6, 2016. ,
Microstructural properties and enhanced photocatalytic performance of Zn doped CeO 2 nanocrystals, Sci. Rep, 2017. ,
Crystalline nano-coatings of fluorine-substituted hydroxyapatite produced by magnetron sputtering with high plasma confinement, Surf. Coat. Technol, vol.264, pp.163-174, 2015. ,
Uniform luminescent carbon nanodots prepared by rapid pyrolysis of organic precursors confined within nanoporous templating structures, vol.117, pp.437-446, 2017. ,
Carbon felt interlayer derived from rice paper and its synergistic encapsulation of polysulfides for lithium-sulfur batteries, Appl. Surf. Sci, vol.441, pp.914-922, 2018. ,
Facile alcohothermal synthesis, size-dependent ultraviolet absorption, and enhanced CO conversion activity of ceria nanocrystals, J. Phys. Chem. B, vol.107, pp.10159-10167, 2003. ,
Adsorption of uranium (VI) from aqueous solution using a novel graphene oxide-activated carbon felt composite, J. Environ. Radioact, vol.126, pp.253-258, 2013. ,
X-ray photoelectron spectroscopy on uranium oxides: A comparison between bulk and thin layers, J. Nucl. Mater, vol.294, pp.168-174, 2001. ,
Exploiting XPS for the identification of sulfides and polysulfides, vol.5, pp.75953-75963, 2015. ,
Grafting of quaternary ammonium groups for uranium(VI) recovery: Application on natural acidic leaching liquor, J. Radioanal. Nucl. Chem, vol.322, pp.519-532, 2019. ,
Study of influencing factors and the mechanism of preparing triazinedithiol polymeric nanofilms on aluminum surfaces, Int. J. Mol. Sci, vol.11, pp.4715-4725, 2010. ,
Combined DFT and XPS investigation of cysteine adsorption on the pyrite (100) surface. Minerals, vol.8, p.366, 2018. ,
Water-soluble polyacrylamide coated-Fe 3 O 4 magnetic composites for high-efficient enrichment of U(VI) from radioactive wastewater, Chem. Eng. J, vol.246, pp.268-276, 2014. ,
Adsorption behavior of U(VI) on doped polyaniline: The effects of carbonate and its complexes, Radiochim. Acta, vol.106, pp.437-452, 2018. ,
Dissociation of alginic acid, Acta Chem. Scand, vol.15, pp.950-952, 1961. ,
Controlled release of bis(phosphonate) pharmaceuticals from cationic biodegradable polymeric matrices, Ind. Eng. Chem. Res, vol.50, pp.5873-5876, 2011. ,
Ion Properties ,
, , p.259, 1997.
Recovery of uranium(VI) from aqueous solution by 2-picolylamine functionalized polystyrene-co-maleic anhydride) resin, J. Colloid Interface Sci, vol.497, pp.385-392, 2017. ,
MCM-41 silica particles grafted with polyacrylonitrile: Modification in to amidoxime and carboxyl groups for enhanced uranium removal from aqueous medium, Microporous Mesoporous Mater, vol.226, pp.117-124, 2016. ,
Preparation, uranium (VI) absorption and reuseability of marine fungus mycelium modified by the bis-amidoxime-based groups, Radiochim. Acta, vol.108, pp.37-49, 2020. ,
Biosorption of uranium on Sargassum biomass, Water Res, vol.33, pp.3357-3363, 1999. ,
Biosorption of uranium(VI) by bi-functionalized low cost biocomposite adsorbent, Desalination, vol.280, pp.354-362, 2011. ,
Efficient uranium(VI) biosorption on grapefruit peel: Kinetic study and thermodynamic parameters, J. Radioanal. Nucl. Chem, vol.292, pp.1303-1315, 2012. ,
Equilibrium, kinetic and thermodynamic studies on the removal of U(VI) by low cost agricultural waste, Colloids Surf. B, vol.111, pp.12-23, 2013. ,
Biosorption and biomineralization of uranium(VI) from aqueous solutions by Landoltia punctata, Spectrosc. Spectral Anal, vol.35, pp.2613-2619, 2015. ,
Study on sorption characteristics of uranium onto biochar derived from eucalyptus wood, Water Air Soil Pollut, vol.228, 2017. ,
Uranium(VI) biosorption by sugar beet pulp: Equilibrium, kinetic and thermodynamic studies, J. Radioanal. Nucl. Chem, vol.322, pp.2065-2078, 2019. ,
Batch and dynamic extraction of uranium(VI) from nitric acid medium by commercial phosphinic acid resin, Tulsion CH-96, J. Radioanal. Nucl. Chem, vol.275, pp.563-570, 2008. ,
Uranium(VI) sorption behavior onto amberlite CG-400 anion exchange resin: Effects of pH, contact time, temperature and presence of phosphate, Ann. Nucl. Energy, vol.48, pp.21-24, 2012. ,
Adsorption of uranium(VI) from aqueous solution by diethylenetriamine-functionalized magnetic chitosan, J. Radioanal. Nucl. Chem, vol.298, pp.1375-1383, 2013. ,
Adsorption of uranium(VI) from sulphate solutions using Amberlite IRA-402 resin: Equilibrium, kinetics and thermodynamics study, Ann. Nucl. Energy, vol.75, pp.132-138, 2015. ,
Phosphonate modified MoS 2 composite material for effective adsorption of uranium(VI) in aqueous solution, J. Radioanal. Nucl. Chem, vol.323, pp.641-649, 2020. ,
Removal of U(VI) from nuclear mining effluent by porous hydroxyapatite: Evaluation on characteristics, mechanisms and performance, Environ ,
A zinc MOF with carboxylate oxygen-functionalized pore channels for uranium(VI) sorption, Eur. J. Inorg. Chem, pp.735-739, 2019. ,
New iron oxide nanoparticles catechol-grafted with bis(amidoxime)s for uranium(VI) depletion of aqueous solution, J. Nanosci. Nanotechnol, vol.19, pp.4911-4919, 2019. ,
Chromium(VI) removal from aqueous solutions by Mg-Al-CO 3 hydrotalcite: Sorption-desorption kinetic and equilibrium studies, Ind. Eng. Chem. Res, vol.43, pp.2209-2215, 2004. ,
On the characterization of acidic and basic surface sites on carbons by various techniques, Carbon, vol.37, pp.1215-1221, 1999. ,
Separation and Spectrophotometric Determination of Elements, p.678, 1986. ,
Mineralogical Characteristics and Leachability of Some Valuable Metals from Abu Zienema Poly-mineralized Carbonaceous Shale, Southwestern Sinai, 2017. ,
Adsorption Calculations and Modeling, p.243, 1994. ,
Insights into the modeling of adsorption isotherm systems, Chem. Eng. J, vol.156, pp.2-10, 2010. ,
Visual MINTEQ Version 3.0 ,
, , 2013.
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