, BRGM, Fiche de Synthèse sur la criticité des Matières Premières Minérales -Le Scandium -Novembre, p.6, 2017.

J. H. Wynne, J. L. Buckley, C. E. Coumbe, J. P. Phillips, and S. Stevenson, Reducing hazardous material and environmental impact through recycling of scandium nanomaterial waste, J. Environ. Sci. Health Part A, vol.43, pp.357-360, 2008.

C. Ruiz-canovas, F. Macias, R. Lopez, and J. Nieto, Mobility of rare earth elements, yttrium and scandium from a phosphogypsum stack: Environmental and economic implications, Sci. Total Environ, vol.618, pp.847-857, 2018.

N. Zhang, H. Li, and X. Liu, Recovery of scandium from bauxite residue-red mud: a review, Rare Met, vol.35, pp.887-900, 2016.

K. Zhou, C. Teng, X. Zhang, C. Peng, and W. Chen, Enhanced selective leaching of scandium from red mud, Hydrometallurgy, vol.182, pp.57-63, 2018.

M. Ochsenkuehn-petropoulou, L. Tsakanika, T. Lymperopoulou, and K. ,

K. Ochsenkuehn, P. Hatzilyberis, C. Georgiou, O. Stergiopoulos, F. Serifi et al., Efficiency of sulfuric acid on selective scandium leachability from bauxite residue, Metals, vol.8, 2018.

C. R. Borra, J. Mermans, B. Blanpain, Y. Pontikes, K. Binnemans et al., Selective recovery of rare earths from bauxite residue by combination of sulfation, roasting and leaching, Miner. Eng, vol.92, pp.151-159, 2016.

Z. Liu and H. Li, Metallurgical process for valuable elements recovery from red mud -a review, Hydrometallurgy, vol.155, pp.29-43, 2015.

R. M. Rivera, B. Xakalashe, G. Ounoughene, K. Binnemans, B. Friedrich et al., Selective rare earth element extraction using high-pressure acid leaching of slags arising from the smelting of bauxite residue, Hydrometallurgy, vol.184, pp.162-174, 2019.

C. R. Borra, Y. Pontikes, K. Binnemans, and T. Van-gerven, Leaching of rare earths from bauxite residue (red mud), Miner. Eng, vol.76, pp.20-27, 2015.

B. Yagmurlu, C. Dittrich, and B. Friedrich, Effect of aqueous media on the recovery of scandium by selective precipitation, Metals, vol.8, 2018.

R. P. Narayanan, N. K. Kazantzis, and M. H. Emmert, Selective process steps for the recovery of scandium from Jamaican bauxite residue, ACS Sustain. Chem. Eng, vol.6, pp.1478-1488, 2018.

D. Avdibegovic, B. Yagmurlu, C. Dittrich, M. Regadio, B. Friedrich et al., Combined multi-step precipitation and supported ionic liquid phase chromatography for the recovery of rare earths from leach solutions of bauxite residues, Hydrometallurgy, vol.180, pp.229-235, 2018.

Q. Ye, G. H. Li, B. N. Deng, J. Luo, M. J. Rao et al., Solvent extraction behavior of metal ions and selective separation Sc 3+ in phosphoric acid medium using P204, Sep. Purif. Technol, vol.209, pp.175-181, 2019.

A. G. Souza, P. Aliprandini, D. C. Espinosa, and J. A. Tenorio, Scandium extraction from nickel processing waste using Cyanex 923 in sulfuric medium, JOM, vol.71, pp.2003-2009, 2019.

M. Sharaf, W. Yoshida, F. Kubota, and M. Goto, Selective extraction of scandium by a long alkyl chain carboxylic acid/organophosphonic ester binary extractant, Solvent Extr. Ion Exch, vol.36, pp.647-657, 2018.

A. A. Korenevsky, V. V. Sorokin, and G. I. Karavaiko, Biosorption of rare earth elements, Process Metallurgy, pp.299-306, 1999.

Y. Hosomomi, Y. Baba, F. Kubota, N. Kamiya, and M. Goto, Biosorption of rare earth elements by Escherichia coli, J. Chem. Eng. Jpn, vol.46, pp.450-454, 2013.

D. L. Ramasamy, S. Porada, and M. Sillanpaa, Marine algae: a promising resource for the selective recovery of scandium and rare earth elements from aqueous systems, Chem. Eng. J, vol.371, pp.759-768, 2019.

K. Kilian, K. Pyrzynska, and M. Pegier, Comparative study of Sc(III) sorption onto carbon-based materials, Solvent Extr. Ion Exch, vol.35, pp.450-459, 2017.

G. Zhou, Q. Li, P. Sun, W. Guan, G. Zhang et al., Removal of impurities from scandium chloride solution using 732-type resin, J. Rare Earths, vol.36, pp.311-316, 2018.

X. Zhu, W. Li, S. Tang, M. Zeng, P. Bai et al., Selective recovery of vanadium and scandium by ion exchange with D201 and solvent extraction using P507 from hydrochloric acid leaching solution of red mud, Chemosphere, vol.175, pp.365-372, 2017.

Z. Zhao, Y. Baba, W. Yoshida, F. Kubota, and M. Goto, Development of novel adsorbent bearing aminocarbonylmethylglycine and its application to scandium separation, J. Chem. Technol. Biotechnol, vol.91, pp.2779-2784, 2016.

N. Van, A. Iizuka, E. Shibata, and T. Nakamura, Study of adsorption behavior of a new synthesized resin containing glycol amic acid group for separation of scandium from aqueous solutions, Hydrometallurgy, vol.165, pp.51-56, 2016.

D. Avdibegovic, M. Regadio, and K. Binnemans, Recovery of scandium(III) from diluted aqueous solutions by a supported ionic liquid phase (SILP), RSC Adv, vol.7, pp.49664-49674, 2017.

H. Cui, J. Chen, H. Li, D. Zou, Y. Liu et al., High-performance polymer-supported extractants with phosphonate ligands for scandium(III) separation, AlChE J, vol.62, pp.2479-2489, 2016.

M. Sharaf, W. Yoshida, F. Kubota, and M. Goto, A novel binary-extractant-impregnated resin for selective recovery of scandium, J. Chem. Eng. Jpn, vol.52, pp.49-55, 2019.

S. Wang, T. Vincent, C. Faur, E. Rodriguez-castellon, and E. , A new method for incorporating polyethyleneimine (PEI) in algal beads: high stability as sorbent for palladium recovery and supported catalyst for nitrophenol hydrogenation, Mater. Chem. Phys, vol.221, pp.144-155, 2019.
URL : https://hal.archives-ouvertes.fr/hal-01937653

S. Lu, L. Chen, M. F. Hamza, C. He, X. Wang et al., Amidoxime functionalization of a poly(acrylonitrile)/silica composite for the sorption of Ga(III) -application to the treatment of Bayer liquor, Chem. Eng. J, vol.368, pp.459-473, 2019.
URL : https://hal.archives-ouvertes.fr/hal-02428222

M. F. Hamza, Y. Wei, H. I. Mira, A. A. Abdel-rahman, and E. , Synthesis and adsorption characteristics of grafted hydrazinyl amine magnetite-chitosan for Ni(II) and Pb(II) recovery, Chem. Eng. J, vol.362, pp.310-324, 2019.
URL : https://hal.archives-ouvertes.fr/hal-02425055

Y. S. Ho and G. Mckay, Pseudo-second order model for sorption processes, Process. Biochem, vol.34, pp.451-465, 1999.

J. Crank, The Mathematics of Diffusion, second, p.414, 1975.

C. Tien, Adsorption Calculations and Modeling, p.243, 1994.

D. Manns, M. Nielsen, A. Bruhn, B. Saake, and A. Meyer, Compositional variations of brown seaweeds Laminaria digitata and Saccharina latissima in Danish waters, J. Appl. Phycol, vol.29, pp.1493-1506, 2017.

A. Deepatana, J. A. Tang, and M. Valix, Comparative study of chelating ion exchange resins for metal recovery from bioleaching of nickel laterite ores, Miner. Eng, vol.19, pp.1280-1289, 2006.

O. I. Shchukina, A. V. Zatirakha, A. S. Uzhel, A. D. Smolenkov, and O. A. Shpigun, Novel polymer-based anion-exchangers with covalently-bonded functional layers of quaternized polyethyleneimine for ion chromatography, Anal. Chim. Acta, vol.964, pp.187-194, 2017.

R. Rodriguez-dorado, C. Lopez-iglesias, C. A. Garcia-gonzalez, G. Auriemma, R. P. Aquino et al., Design of aerogels, cryogels and xerogels of alginate: effect of molecular weight, gelation conditions and drying method on particles' micromeritics, Molecules, vol.24, 2019.

I. Preibisch, P. Niemeyer, Y. Yusufoglu, P. Gurikov, B. Milow et al., Polysaccharide-based aerogel bead production via jet cutting method, Materials, vol.11, 2018.

F. Wu, J. Li, Y. Tian, Y. Su, J. Wang et al., 3D coral-like nitrogen-sulfur co-doped carbon-sulfur composite for high performance lithiumsulfur batteries, Sci. Rep, vol.5, 2015.

C. Doroftei and L. Leontie, Synthesis and characterization of some nanostructured composite oxides for low temperature catalytic combustion of dilute propane, RSC Adv, vol.7, pp.27863-27871, 2017.

B. Jurado-lopez, R. S. Vieira, R. B. Rabelo, M. M. Beppu, J. Casado et al., Formation of complexes between functionalized chitosan membranes and copper: a study by angle resolved XPS, Mater. Chem. Phys, vol.185, pp.152-161, 2017.

Y. B. Sun, X. X. Wang, C. C. Ding, W. C. Cheng, C. L. Chen et al., Direct synthesis of bacteria-derived carbonaceous nanofibers as a highly efficient material for radionuclides elimination, ACS Sustain. Chem. Eng, vol.4, pp.4608-4616, 2016.

M. C. Ortega-liebana, N. X. Chung, R. Limpens, L. Gomez, J. L. Hueso et al., Uniform luminescent carbon nanodots prepared by rapid pyrolysis of organic precursors confined within nanoporous templating structures, Carbon, vol.117, pp.437-446, 2017.

Y. W. Zhang, R. Si, C. S. Liao, and C. H. Yan, Facile alcohothermal synthesis, size-dependent ultraviolet absorption, and enhanced CO conversion activity of ceria nanocrystals, J. Phys. Chem. B, vol.107, pp.10159-10167, 2003.

E. O. Lopez, A. L. Rossi, B. S. Archanjo, R. O. Ospina, A. Mello et al., Crystalline nano-coatings of fluorine-substituted hydroxyapatite produced by magnetron sputtering with high plasma confinement, Surf. Coat. Technol, vol.264, pp.163-174, 2015.

M. A. Khan, W. Khan, M. Ahamed, and A. N. Alhazaa, Microstructural properties and enhanced photocatalytic performance of Zn doped CeO 2 nanocrystals, Sci. Rep, vol.7, 2017.

K. Yang, L. Zhong, R. Guan, M. Xiao, D. Han et al., Carbon felt interlayer derived from rice paper and its synergistic encapsulation of polysulfides for lithium-sulfur batteries, Appl. Surf. Sci, vol.441, pp.914-922, 2018.

F. Wang, H. Li, Q. Liu, Z. Li, R. Li et al., A graphene oxide/amidoxime hydrogel for enhanced uranium capture, Sci. Rep, vol.6, 2016.

S. J. Yuan, F. J. Xu, E. T. Kang, and S. O. Pehkonen, Modification of surface-oxidized copper alloy by coupling of viologens for inhibiting microbiologically influenced corrosion, J. Electrochem. Soc, vol.154, pp.645-657, 2007.

J. Baltrusaitis, P. M. Jayaweera, and V. H. Grassian, XPS study of nitrogen dioxide adsorption on metal oxide particle surfaces under different environmental conditions, Phys. Chem. Chem. Phys, vol.11, pp.8295-8305, 2009.

L. Qie, W. Chen, X. Xiong, C. Hu, F. Zou et al., Sulfur-doped carbon with enlarged interlayer distance as a high-performance anode material for sodium-ion batteries, Adv. Sci, vol.2, 2015.

A. Liu, G. Liu, H. Zhu, H. Song, B. Shin et al., Waterinduced scandium oxide dielectric for low-operating voltage n-and p-type metaloxide thin-film transistors, Adv. Funct. Mater, vol.25, pp.7180-7188, 2015.

P. Araujo, G. B. Belini, G. P. Mambrini, F. M. Yamaji, and W. R. Waldman, Thermal degradation of calcium and sodium alginate: a greener synthesis towards calcium oxide micro/nanoparticles, Int. J. Biol. Macromol, 2019.

E. Membere and P. Sails, Thermochemical characterization of brown seaweed, Laminaria digitata from UK shores, J. Anal. Appl. Pyrol, vol.131, pp.42-51, 2018.

L. F. Chen, X. K. Bian, and X. F. Lu, Removal of strontium from simulated low-level radioactive wastewater by nanofiltration, Water Sci. Technol, vol.78, pp.1733-1740, 2018.

A. Haug, Dissociation of alginic acid, Acta Chem. Scand, vol.15, pp.950-952, 1961.

K. D. Demadis, M. Paspalaki, and J. Theodorou, Controlled release of bis(phosphonate) pharmaceuticals from cationic biodegradable polymeric matrices, Ind. Eng. Chem. Res, vol.50, pp.5873-5876, 2011.

H. Sun, F. S. Cannon, and X. He, Enhanced trifluoroacetate removal from groundwater by quaternary nitrogen-grafted granular activated carbon, Sci. Total Environ, vol.660, pp.577-585, 2019.

Z. J. Li, A. Toyoshima, K. Tsukada, and Y. Nagame, Ion-exchange behavior of Zr and Hf as homologues of element 104, Rf, in H 2 SO 4 and H 2 SO 4 /HClO 4 mixed solutions, Radiochim. Acta, vol.98, pp.7-12, 2010.

S. Bao, W. Hawker, and J. Vaughan, Scandium loading on chelating and solvent impregnated resin from sulfate solution, Solvent Extr. Ion Exch, vol.36, pp.100-113, 2018.

W. W. Wang, Y. Pranolo, and C. Y. Cheng, Recovery of scandium from synthetic red mud leach solutions by solvent extraction with D2EHPA, Sep. Purif. Technol, vol.108, pp.96-102, 2013.

N. K. Lazaridis, T. A. Pandi, and K. A. Matis, Chromium(VI) removal from aqueous solutions by Mg-Al-CO 3 hydrotalcite: sorption-desorption kinetic and equilibrium studies, Ind. Eng. Chem. Res, vol.43, pp.2209-2215, 2004.

X. Sun, B. Peng, Y. Ji, J. Chen, and D. Li, The solid-liquid extraction of yttrium from rare earths by solvent (ionic liquid) impreganated resin coupled with complexing method, Sep. Purif. Technol, vol.63, pp.61-68, 2008.

J. Ma, Z. Wang, Y. Shi, and Q. Li, Synthesis and characterization of lysine-modified SBA-15 and its selective adsorption of scandium from a solution of rare earth elements, RSC Adv, vol.4, pp.41597-41604, 2014.

S. Iftekhar, V. Srivastava, and M. Sillanpaa, Enrichment of lanthanides in aqueous system by cellulose based silica nanocomposite, Chem. Eng. J, vol.320, pp.151-159, 2017.

S. Giret, Y. Hu, N. Masoumifard, J. Boulanger, E. Juere et al., Selective separation and preconcentration of scandium with mesoporous silica, ACS Appl. Mater. Interfaces, vol.10, pp.448-457, 2018.

M. Pegier, K. Kilian, and K. Pyrzynska, Enrichment of scandium by carbon nanotubes in the presence of calcium matrix, Microchem. J, vol.137, pp.371-375, 2018.

D. L. Ramasamy, V. Puhakka, E. Repo, and M. Sillanpaa, Selective separation of scandium from iron, aluminium and gold rich wastewater using various amino and nonamino functionalized silica gels -a comparative study, J. Clean. Prod, vol.170, pp.890-901, 2018.

Q. Yu, S. Ning, W. Zhang, X. Wang, and Y. Wei, Recovery of scandium from sulfuric acid solution with a macro porous TRPO/SiO 2 -P adsorbent, Hydrometallurgy, vol.181, pp.74-81, 2018.